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Jinbe tries to protect Luffy but is injured. As Akainu goes for the finishing blow on Jinbe, Luffy glares at him with intense fury and screams, "Don't do it!" A shockwave blasts out from Luffy, knocking back the surrounding Marines and stopping Akainu in his tracks for a split second.
Luffy unlocks the power of a at the moment he is most powerless to save his brother.
The moment unleashed his Conqueror’s Haki at Marineford remains one of the most iconic turning points in the One Piece series. Occurring during Episode 478 , titled "To the Promise He Made! Luffy and Coby Face Off," and continuing into Episode 479 , this scene marks the definitive moment when the world’s greatest powers recognized Luffy not just as a rookie, but as a legitimate threat with the potential to stand at the top of the pirate world. The Scene: A Desperate Burst of Will luffy using haki in marineford episode
Fans often ask: "If Luffy had Conqueror’s Haki at Marineford, why didn't he use it to save Ace?"
Luffy is exhausted and collapsing from the intensity of the war. As he falls to the ground, the executioners prepare to kill Ace. Luffy screams in desperation. Jinbe tries to protect Luffy but is injured
The war at Marineford has reached its climax as Luffy, determined to save his brother Ace, faces off against the World Government's powerful forces. As he navigates through the intense battlefield, Luffy becomes increasingly frustrated with his inability to land a hit on the enemy.
In Episode 476 , Luffy stretches his arm to punch Mihawk. He briefly visualizes his arm being cut off (Observation Haki intuition) and stops his attack. However, he does not successfully use Armament Haki to hit Mihawk; he dodges instead. The moment unleashed his Conqueror’s Haki at Marineford
At this point in the story (2011 in the anime, 2010 in the manga), the concept of Haoshoku Haki (Conqueror’s Haki) had only been whispered about. We saw Shanks use it on the Moby Dick to crack Whitebeard’s ship. But Luffy? Luffy was supposed to be a rookie.